I don't know much about theory in this subject, but is it supposed to be augmented 4th or diminished 5th? Or which is the more precise?
The interval between an f-natural and a b-natural is called a tritone or an augmented fourth; the diminished fifth is the interval between a b-natural and an f-natural. Although they are both supposed to be avoided in western musical theory, it is the augmented fourth which should be avoided at all costs, whereas there is license to use the diminished fifth occasionally. The locrian mode (b-natural to b-natural) was invented long after all the Greek (Gregorian) modes, and is not truly one of them, since it contains a tritone.